Chemical Reaction Engineering
For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase
Surface reaction between A in the gas phase and absorbed B
Surface reaction between absorbed A and absorbed B
Desorption of C

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Chemical Reaction Engineering
A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that __________ in the two reactors.

Conversion in both will be the same but concentrations will be different
Both conversion as well as concentration are same
Both the conversion as well as concentrations will be different
None of these

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