Chemical Reaction Engineering
In which of the following gaseous phase reversible reactions, the product yield can not be increased by the application of high pressure?

N + 3H₂ ⇋ 2NH₃
N₂ + O₂ ⇋ 2NO
2SO₂ + O₂ ⇋ 2SO₃
PCl3 + Cl₂ ⇋ PCl5

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Chemical Reaction Engineering
Which of the following is not a dimension-less group used in catalysis ? (where, D = dispersion co-efficient, cm² /sec.D1 = diffusion co-efficient; cm²/sec L = length of the reactor, cm t = time, sec, v = volumetric flow rate, cm³/sec . V = volume, cm³.)

Reactor dispersion number (D/vL)
Reduced time (vt/V)
Thiele modulus (L√(k/D1)
None of these

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