Chemical Reaction Engineering
For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant

Decreases with pressure
Increases with pressure
Increases /decreases with pressure depending on the stoichiometric co-efficients of the reaction
Is independent of pressure

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Chemical Reaction Engineering
For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase
Surface reaction between absorbed A and absorbed B
Desorption of C
Surface reaction between A in the gas phase and absorbed B

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