Chemical Reaction Engineering
In case of the irreversible unimolecular type, first order reaction, the fractional conversion at any time for constant volume system as compared to variable volume system is

Less
More
Either A or B, depends on other factors
Same

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Chemical Reaction Engineering
The reactions of high molecularity are rare, because

Many body collisions are not favoured energetically
Of low probability of many body collisions
Of requirement of very large concentration for such reactions
Of very large activation energy of many bodies

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