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Chemical Reaction Engineering

Chemical Reaction Engineering
Rate of an autocatalytic chemical reaction is a function of

Temperature only
Pressure only
All of these
Composition only

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Chemical Reaction Engineering
Inversion of cane sugar is an example of

Bimolecular reaction with second order
Bimolecular reaction with first order
Unimolecular reaction with first order
Unimolecular reaction with second order

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Chemical Reaction Engineering
In which of the following reactions, thee-quilibrium will shift to the right, if the total pressure is increased?

N₂ + O₂ ⇋ 2NO
H₂ + I₂ ⇋ 2HI
H₂ + Cl₂ ⇋ 2HCl
N₂O₄ ⇋ 2 NO₂

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Chemical Reaction Engineering
A batch reactor is characterised by

Constant residence time
Variation in reactor volume
Variation in extent of reaction and properties of the reaction mixture with time
Very low conversion

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Chemical Reaction Engineering
A first order gaseous phase reaction is catalysed by a non-porous solid. The kinetic rate constant and the external mass transfer co-efficients are k and kg respectively. The effective rate constant (keff) is given by

keff = k + kg
keff = (kkg)1/2
1/keff = 1/k + 1/kg
keff = (k+ kg)/2

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Chemical Reaction Engineering
If the rate of a chemical reaction becomes slower at a given temperature, then the

Free energy of activation is lower
Initial concentration of the reactants remains constant
Entropy changes
Free energy of activation is higher

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