Mass Transfer
In case of steam distillation, the steam leaving the liquid is not completely saturated with distillate vapour, because

Total pressure is less
Temperature is less
Mixing of steam with the material being vaporised is not so intimate as to result in equilibrium condition
Saturated steam is used for steam distillation

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Mass Transfer
A distillation column with N plates is being operated under normal conditions. At some point of time, the operation is shifted to total reflux condition (i.e., no product and residue are being withdrawn and feed to the column is stopped). At the new steady state,

The top and bottom compositions are unchanged with and without total reflux
The top and bottom compositions correspond to the maximum enrichment available
Reboiler load and condenser load are minimum
Composition of vapors and that of liquid do not vary throughout the column

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Mass Transfer
One mole feed of a binary mixture of a given composition is flash vaporised at a fixed P and T. If Raoult's law is obeyed, then changing the feed composition would effect

Neither the product composition nor the fraction vaporised
The product composition as well as the fraction vaporised
The fraction vaporised but not the product composition
The product composition but not the fraction vaporised

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