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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
In a reversible process

DE - dW = Tds
Tds - dW + dE >0
DW - dE = Tds
Tds = dE + dW

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Chemical Engineering Thermodynamics
In which of the following reaction equilibria, the value of equilibrium constant Kp will be more than is Kc?

None of these
2HI ⇋ H₂ + I₂
N₂O₄ ⇋ 2NO₂
2SO₂ + O₂ ⇋ 2SO₃

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Chemical Engineering Thermodynamics
In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is

Unpredictable; depends on the particular reaction
Less
Same
More

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Chemical Engineering Thermodynamics
"The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture". This is

The statement as per Gibbs-Helmholtz
Henry's law
Called Lewis-Randall rule
None of these

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Chemical Engineering Thermodynamics
As the time is passing, entropy of the universe

Remains constant
Is decreasing
Data insufficient, can't be predicted
Is increasing

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Chemical Engineering Thermodynamics
Which of the following is not correct for a reversible adiabatic process?

TVγ-1 = constant
P1-γ.TY = constant
None of these
PVγ = constant

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