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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
In a reversible process

DW - dE = Tds
Tds - dW + dE >0
DE - dW = Tds
Tds = dE + dW

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Chemical Engineering Thermodynamics
The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv), depends upon its

Pressure
Temperature
All of these
Volume

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂S/∂P)T = -(∂V/∂T)P
(∂T/∂V)S = -(∂P/∂S)V
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂V)T = (∂P/∂T)V

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Chemical Engineering Thermodynamics
Work done in an adiabatic process between two states depends on the

Initial state only
End states only
None of these
Rate of heat transmission

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Chemical Engineering Thermodynamics
Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure.

Fugacity
Partial pressure
Activity co-efficient
A, B, and C

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Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

DQ = CpdT + Vdp
Tds = dE - PdV
DE = Tds - PdV
DQ = CvdT + PdV

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