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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
In a reversible process

Tds = dE + dW
Tds - dW + dE >0
DE - dW = Tds
DW - dE = Tds

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Chemical Engineering Thermodynamics
Helmholtz free energy (A) is defined as

None of these
A = H - TS
A = E - TS
A = H + TS

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Chemical Engineering Thermodynamics
A closed system is cooled reversibly from 100°C to 50°C. If no work is done on the system

Its internal energy (U) decreases and its entropy (S) increases
U is constant but S decreases
U decreases but S is constant
U and S both decreases

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Chemical Engineering Thermodynamics
For an ideal solution, the value of activity co-efficient is

1
< 1
> 1

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Chemical Engineering Thermodynamics
The reaction A (l) R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The number of degrees of freedom are

3
1
2

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Chemical Engineering Thermodynamics
Any substance above its critical temperature exists as

Saturated vapour
Gas
Liquid
Solid

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