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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
If heat contents of CH₄, C₂H₄ and C₃H₈ are -17.9, 12.5 and -24.8 kcal/mole respectively, than ΔH for the reaction CH₄(g) + C₂H₄(g) ⇋ C₃H₈(g) will be __________ Kcal.

-30.2
55.2
-19.4
-55.2

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Chemical Engineering Thermodynamics
Compound having large heat of formation is

Less stable
Either more or less stable ; depends on the compound
Not at all stable (like nascent O₂)
More stable

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Chemical Engineering Thermodynamics
The free energy change for a chemical reaction is given by (where, K = equilibrium constant)

T lnK
-R lnK
RT lnK
-RT lnK

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Chemical Engineering Thermodynamics
The kinetic energy of gas molecule is zero at

0°C
100°C
-273°C
273°C

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Chemical Engineering Thermodynamics
The expression, nRT In P₁/P₂ , is for the____of an ideal gas.

Work done under isothermal condition
Work done under adiabatic contition
Co-efficient of thermal expansion
Compressibility

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Chemical Engineering Thermodynamics
If the molar heat capacities (Cp or Cv) of the reactants and products of a chemical reaction are identical, then, with the increase in temperature, the heat of reaction will

Decrease
Increase
Remain unaltered
Increase or decrease ; depends on the particular reaction

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