Stoichiometry
Hess's law of constant heat summation is based on conservation of mass. It deals with

Changes in heat of reaction
Reaction rate
None of these
Equilibrium constant

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Stoichiometry
Heat of neutralisation of a strong acid and strong base is always a constant value, i.e., 57 KJ/Kg mole. This is because

Only OH⁻ and H⁺ ions react in every case
The salt formed does not hydrolyse
The strong base and strong acid reacts in aqueous solution
The strong base and strong acid reacts completely

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