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Chemical Reaction Engineering

Chemical Reaction Engineering
Helium-mercury method can be used to determine the __________ of the catalyst particle.

Solid density
Porosity
Pore volume
All of these

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Chemical Reaction Engineering
The decomposition of A into B is represented by the exothermic reaction, A ⇋ 2B. To achieve maximum decomposition, it is desirable to carry out the reaction.

At low P and low T
At low P and high T
At high P and low T
At high P and high T

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Chemical Reaction Engineering
Overall rate of reaction in a heterogenous catalytic reaction depends upon the mass and energy transfer from the fluid to solid surface and its rate of reaction is usually __________ the concentration of catalyst, if it does not entail a chain mechanism.

Independent of
Inversely proportional to
Proportional to
Proportional to the square of

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Chemical Reaction Engineering
Rate constant 'k' and absolute temperature 'T' are related by collision theory (for bimolecular) as

k ∝ √T
k ∝ exp(-E/RT)
k ∝ T1.5
k ∝ T

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Chemical Reaction Engineering
A pulse tracer is introduced in an ideal CSTR (with a mean residence time ι) at time, t = 0. The time taken for the exit concentration of the tracer to reach half of its initial value will be

0.693τ
τ/0.693
2τ
0.5τ

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Chemical Reaction Engineering
If the rate of a chemical reaction becomes slower at a given temperature, then the

Free energy of activation is lower
Free energy of activation is higher
Entropy changes
Initial concentration of the reactants remains constant

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