Chemical Reaction Engineering
For the non-catalytic reaction of particles with surrounding fluid, the time needed to achieve the same fractional conversion for particles of different but unchanging sizes is proportional to the square of particle diameter, when the __________ is the controlling resistance.

Either A, B or C
Chemical reaction
Film diffusion
Diffusion through ash layer

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Chemical Reaction Engineering
The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)

E + ΔHA - ΔHR
ΔHA + ΔHR
E
E + ΔHA

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