Chemical Reaction Engineering
Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants ; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is

2
3
0
1

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Chemical Reaction Engineering
For a heterogeneous catalytic reaction

A relatively small amount of catalyst can cause the conversion of large amount of reactants which does not mean that catalyst concentration is important
The catalyst does not form an intermediate complex with the reactant
The surface of the catalyst does not play an important role during reaction
Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction

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