Chemical Reaction Engineering
For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

Surface reaction between absorbed A and absorbed B
Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase
Desorption of C
Surface reaction between A in the gas phase and absorbed B

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Chemical Reaction Engineering
For a tubular reactor with space time 'τ' and residence time 'θ', the following statement holds good.

τ = θ , when the fluid density changes in the reactor
τ and θ are always equal
τ = θ , for a non-isothermal reactor
τ = θ , for an isothermic tubular reactor in which the density of the process fluid is constant

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