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Chemical Reaction Engineering

Chemical Reaction Engineering
Rate constant 'k' and absolute temperature 'T' are related by collision theory (for bimolecular) as

k ∝ T1.5
k ∝ √T
k ∝ exp(-E/RT)
k ∝ T

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Chemical Reaction Engineering
A catalyst in a chemical reaction __________ free energy change in the reaction.

Either A or B; depends on the type of catalyst
Increases
Neither A nor B
Decreases

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Chemical Reaction Engineering
According to the 'law of mass action', the rate of reaction is directly proportional to the

Volume of the reaction vessel
Equilibrium constant
Nature of the reactants
Molar concentration of the reactants

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Chemical Reaction Engineering
The equilibrium constant of a catalytic chemical reaction __________ due to the presence of a catalyst.

Increases
Unpredictable from the data
Decreases
Remains unaffected

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Chemical Reaction Engineering
A first order reaction A → B occurs in an isothermal porous catalyst pellet of spherical shape. If the concentration of A at the centre of the pellet is much less than at the external surface, the process is limited by

External mass transfer
Reaction
Diffusion within the pellet
None of these

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Chemical Reaction Engineering
If the time required to change the concentration of reactant to half its original value is independent of the initial concentration, the order of reaction is

Three
One
Zero
Two

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