Chemical Engineering Thermodynamics
A refrigeration cycle is a reversed heat engine. Which of the following has the maximum value of the co-efficient of performance (COP) for a given refrigeration effect?

Vapor compression cycle using expansion valve
Carnot refrigeration cycle
Air refrigeration cycle
Vapor compression cycle using expansion engine

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Chemical Engineering Thermodynamics
Gibbs-Duhem equation

Applies only to binary systems
States that n₁dμ₁ + n₂dμ₂ + ....njdμj = 0, for a system of definite composition at constant temperature and pressure
Finds no application in gas-liquid equilibria involved in distillation
None of these

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