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CHEMICAL ENGINEERING THERMODYNAMICS

Chemical Engineering Thermodynamics
For a constant volume process

dE = CpdT
dQ = dE + pdV
dW = pdV
dE = CvdT

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Chemical Engineering Thermodynamics
Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?

DQ = CvdT + PdV
Tds = dE - PdV
DE = Tds - PdV
DQ = CpdT + Vdp

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Chemical Engineering Thermodynamics
For an exothremic reaction

Only enthalpy change (ΔH) is negative
Enthalpy change is zero
Both ΔH and ΔE are negative
Only internal energy change (ΔE) is negative

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Chemical Engineering Thermodynamics
For an ideal gas, the enthalpy

Increases with rise in pressure
Is independent of pressure
Decreases with rise in pressure
Is a path function

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Chemical Engineering Thermodynamics
Refrigerants commonly used for domestic refrigerators are

Propane
NH₃ or CO₂
Ethyl chloride or methyle chloride
Freon-12

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