Chemical Reaction Engineering
Brunaur, Emmet and Teller (BET) equation is used to determine the specific surface area of a porous particle but not the pore volume & the porosity of the catalyst bed. Which of the following postulates is not used to derive BET equation?

Langmuir
The adsorbed layer may be polymolecular in thickness and the heat of adsorption in each layer (except the first one) is involved in each of the evaporation process
None of these
There is no dynamic equilibrium between successive layer

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Chemical Reaction Engineering
In Langmuir treatment of adsorption,

All the adsorption does not take place by the same mechanism
Whole surface of the catalyst is essentially uniform and the adsorbed molecule has no effect on the rate of adsorption per site
Extent of adsorption is more than one complete monomolecular layer on the surface
Whole surface of the catalyst does not have the same activity for adsorption and there is attraction between the adsorbed molecule

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Chemical Reaction Engineering
The reaction rate almost gets doubled for 10°C rise in temperature. This is due to the fact that the

Increased temperature reduces the activation energy
Collision frequency increases
Fraction of molecules having threshold energy increases
Value of threshold energy decreases

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