Chemical Reaction Engineering
Brunaur, Emmet and Teller (BET) equation is used to determine the specific surface area of a porous particle but not the pore volume & the porosity of the catalyst bed. Which of the following postulates is not used to derive BET equation?

The adsorbed layer may be polymolecular in thickness and the heat of adsorption in each layer (except the first one) is involved in each of the evaporation process
Langmuir
None of these
There is no dynamic equilibrium between successive layer

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Chemical Reaction Engineering
The reaction rate almost gets doubled for 10°C rise in temperature. This is due to the fact that the

Value of threshold energy decreases
Collision frequency increases
Increased temperature reduces the activation energy
Fraction of molecules having threshold energy increases

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