Chemical Reaction Engineering
Brunaur, Emmet and Teller (BET) equation is used to determine the specific surface area of a porous particle but not the pore volume & the porosity of the catalyst bed. Which of the following postulates is not used to derive BET equation?

Langmuir
None of these
There is no dynamic equilibrium between successive layer
The adsorbed layer may be polymolecular in thickness and the heat of adsorption in each layer (except the first one) is involved in each of the evaporation process

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Chemical Reaction Engineering
The rate of the heterogenous catalytic reaction A(g) + B(g) ? C(g) is given by -rA = k.KA.pA.PB/(1 + KA.PA + Kc.pc), where KA and Kc are the adsorption equilibrium constants. The rate controlling step for this reaction isA. absorption of A.

Surface reaction between absorbed A and absorbed B
Surface reaction between A in the gas phase and absorbed B
Surface reaction between absorbed A and B in the gas phase
Absorption of A

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