Stoichiometry
A very dilute solution is prepared by dissolving 'x1' mole of solute in 'x2' mole of a solvent. The mole fraction of solute is approximately equal to

1 - (x1/x2)
1/x2
X2/x1
X1/x2

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Stoichiometry
According to Raoult's law, "The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component." Raoult's law is not applicable under the following assumption/condition.

No component is concentrated at the surface of the solution
In the formation of solution, chemical combination/molecular association between unlike molecules takes place
The component molecules are non polar and are of almost equal size
The attractive forces between like and unlike molecules are almost equal

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