Chemical Reaction Engineering
In Langmuir treatment of adsorption,

All the adsorption does not take place by the same mechanism
Extent of adsorption is more than one complete monomolecular layer on the surface
Whole surface of the catalyst does not have the same activity for adsorption and there is attraction between the adsorbed molecule
Whole surface of the catalyst is essentially uniform and the adsorbed molecule has no effect on the rate of adsorption per site

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Chemical Reaction Engineering
In solid catalysed reactions the diffusional effects are more likely to affect the overall rate of reaction for

Slow reactions in catalyst of large pore diameter
Fast reactions in catalyst of small pore diameter
Slow reactions in catalyst of small pore diameter
Fast reaction in catalyst of large pore diameter

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