Chemical Reaction Engineering
Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants ; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is

2
1
3
0

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Chemical Reaction Engineering
An irreversible aqueous phase reaction, A + B → P, is carried out in an adiabatic mixed flow reactor. A feed containing 4kmole/m³ of each A and B enters the reactor at 8m³ /hr. If the temperature of the exit stream is never to exceed 390 K, what is the maximum inlet feed temperature allowed?(Data: Heat of reaction = - 50 kJ/mole, Density of the reacting mixture = 1000kg/m³, Specific heat of reacting mixture = 2kJ/kg.K)The above data can be assumed to be independent of temperature and composition.

290
390
190
490

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Chemical Reaction Engineering
For a heterogeneous catalytic reaction

The surface of the catalyst does not play an important role during reaction
A relatively small amount of catalyst can cause the conversion of large amount of reactants which does not mean that catalyst concentration is important
Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction
The catalyst does not form an intermediate complex with the reactant

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