Fuels and Combustion
A carbonaceous fuel (containing no H₂ or hydrocarbons) is burnt and the resulting flue gas contains 21% CO₂. It means that

Complete combustion of fuel has taken place
No excess air has been used for combustion
21% excess air has been used for combustion
21% excess oxygen has been used for combustion

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Fuels and Combustion
Fuel gases containing hydrocarbons (ie.g. coke oven gas) are not preheated before burning, mainly because

There are chances of explosion during preheating
It reduces its calorific value tremendously
It reduces its flame temperature tremendously
The hydrocarbons crack thereby choking and fouling the heat transfer surface by carbon soot

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