Chemistry
A balloon filled with helium rises in air because

Helium pushes down on the air below the balloon
The balloon is weightless
Helium is less dense than air
Air exerts an upward force on the balloon

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Chemistry
Photo chemical smog is a resultant of the reaction among

NO2, O3 and peroxy acetyl nitrate in the presence of Sunlight
CO, CO2 and NO2at low temperature
CO, O2 and peroxy acetyl nitrate in the presence of Sunlight
High concentration of NO2, O3, and CO in the evening

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