Chemical Reaction Engineering
Which one is the rate controlling step in a solid-gas non-catalytic reaction occurring at very high temperature?

Chemical reaction
Pore diffusion
Ash layer diffusion
Film diffusion

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Chemical Reaction Engineering
For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

Desorption of C
Surface reaction between A in the gas phase and absorbed B
Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase
Surface reaction between absorbed A and absorbed B

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