Chemical Reaction Engineering
Brunaur, Emmet and Teller (BET) equation is used to determine the specific surface area of a porous particle but not the pore volume & the porosity of the catalyst bed. Which of the following postulates is not used to derive BET equation?

The adsorbed layer may be polymolecular in thickness and the heat of adsorption in each layer (except the first one) is involved in each of the evaporation process
Langmuir
There is no dynamic equilibrium between successive layer
None of these

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Chemical Reaction Engineering
For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

Desorption of C
Surface reaction between absorbed A and absorbed B
Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase
Surface reaction between A in the gas phase and absorbed B

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