NMR Spectroscopy
When placed in a magnetic field, all the random spins of the nuclei

reverse direction
stop
rotate to 90° away from the induced field
align with the magnetic field

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NMR Spectroscopy
Why is it important to use a deuterated solvent?

NMR uses least of this solvent
Expensive solvents work best with NMR
So the spectrometer can lock onto the sample to prevent the spectrum from drifting during aquisition
They dissolve polymer the fastest

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NMR Spectroscopy
What is shielding in NMR?

Blocking parts of a molecule from Rf radiation
When the magnetic moment of an atom blocks the full induced magnetic field from surrounding nuclei
Using a curved piece of metal to block an opponents attack
Putting metal around an Rf source

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NMR Spectroscopy
All hydrogen atoms

have the same resonance frequency
are attached to carbon
resonate at different frequencies depending on their environment.
resonate at about the same frequency as carbon

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NMR Spectroscopy
Coupling causes the peaks in 1H NMR spectra to be split into

multiple peaks equal to the number of hydrogens on surrounding atoms
multiple peaks equal to the number of hydrogen on surrounding atoms, plus one
two peaks
multiple peaks equal to the number of surrounding carbon atoms

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