Chemical Reaction Engineering
The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)

E
ΔHA + ΔHR
E + ΔHA - ΔHR
E + ΔHA

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Chemical Reaction Engineering
Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants ; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is

Chemical Reaction Engineering
A space velocity of 5 hr⁻¹ means that

A fixed conversion of a given batch of feed takes 5 hours
Cent per cent conversion can be achieved in at least 5 hours
Five reactor volumes of feed (at specified conditions) are being fed into the reactor per hour
After every 5 hours, reactor is being filled with the feed

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