Chemical Reaction Engineering
For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase
Surface reaction between A in the gas phase and absorbed B
Surface reaction between absorbed A and absorbed B
Desorption of C

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Chemical Reaction Engineering
The reaction A → B is conducted in an adiabatic plug flow reactor (PFR). Pure A at a concentration of 2 kmol/m³ is fed to the reactor at the rate of 0.01 m³ /s and at a temperature of 500 K. If the exit conversion is 20%, then the exit temperature (in k)is (Data: Heat of reaction at 298 K = - 50000 kJ/ kmole of A reacted Heat capacities CPA = CPB = 100kJ/kmole. K (may be assumed to be independent of temperature))

400
1000
600
500

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Chemical Reaction Engineering
In a zero order reaction, reactants concentration does not change with time and the

Time for half change is independent of the initial concentration
Time for completion of the reaction is independent of the initial concentration
Reaction rate is trebled when the initial concentration is trebled
Time for half change is half the time taken for completion of the reaction

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