Chemical Reaction Engineering
The rate constant of a chemical reaction increases by 100 times when the temperature is increased from 400 °K to 500 °K. Assuming transition state theory is valid, the value of E/R is

9210°K
8987°K
8764°K
8621°K

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Chemical Reaction Engineering
The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)

E + ΔHA - ΔHR
E
E + ΔHA
ΔHA + ΔHR

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