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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The quantitative effect of temperature on chemical equilibrium is given by the

Arhenius equation
Le-Chatelier's principle
None of these
Vant-Hoff equation

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Chemical Engineering Thermodynamics
Entropy of a substance remains constant during a/an __________ change.

Reversible isothermal
Irreversible isothermal
Reversible adiabatic
None of these

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Chemical Engineering Thermodynamics
The following heat engine produces power of 100000 kW. The heat engine operates between 800 K and 300 K. It has a thermal efficiency equal to 50% of that of the Carnot engine for the same temperature. The rate at which heat is absorbed from the hot reservoir is

320, 000 kW
200, 000 kW
100, 000 kW
160, 000 kW

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂S/∂P)T = -(∂V/∂T)P
(∂S/∂V)T = (∂P/∂T)V
(∂T/∂V)S = -(∂P/∂S)V
(∂V/∂S)P = (∂T/∂P)S

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Chemical Engineering Thermodynamics
For an ideal solution, the value of activity co-efficient is

> 1
1
< 1

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Chemical Engineering Thermodynamics
The activity of an ideal gas is numerically __________ its pressure.

Less than
Data insufficient, can't be predicted
Equal to
More than

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