Chemistry
The minimum energy required for an effective collision is

Threshold energy
Free energy
Internal energy
Activation energy

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Chemistry
Photo chemical smog is a resultant of the reaction among

NO2, O3 and peroxy acetyl nitrate in the presence of Sunlight
CO, O2 and peroxy acetyl nitrate in the presence of Sunlight
High concentration of NO2, O3, and CO in the evening
CO, CO2 and NO2at low temperature

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