Fuels and Combustion
The main function of primary air in pulverised coal fired burner is to

Have proper combustion by supplying it around the burner
Preheat the tertiary air used for complete combustion of CO to CO₂
Dry and transport the coal
Burn CO to CO₂

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Fuels and Combustion
A carbonaceous fuel (containing no H₂ or hydrocarbons) is burnt and the resulting flue gas contains 21% CO₂. It means that

21% excess oxygen has been used for combustion
No excess air has been used for combustion
21% excess air has been used for combustion
Complete combustion of fuel has taken place

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