Chemical Reaction Engineering
A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that __________ in the two reactors.

Both conversion as well as concentration are same
None of these
Conversion in both will be the same but concentrations will be different
Both the conversion as well as concentrations will be different

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Chemical Reaction Engineering
The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)

E + ΔHA
ΔHA + ΔHR
E
E + ΔHA - ΔHR

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