Chemical Reaction Engineering
The increase in the rate of reaction with temperature is due to

Increase in the number of effective collisions
None of these
Decrease in activation energy
Increase in the average kinetic energy of the reacting molecules

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Chemical Reaction Engineering
The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)

E + ΔHA
ΔHA + ΔHR
E + ΔHA - ΔHR
E

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