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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
The freezing point of a liquid decreases when the pressure is increased, if the liquid __________ while freezing.

Expands
Does not change in volume
Contracts
Either A, B or C

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Chemical Engineering Thermodynamics
When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is

Same in both the phases
More in vapour phase
More in liquid phase
Replaced by chemical potential which is more in vapour phase

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Chemical Engineering Thermodynamics
When a gas is subjected to adiabatic expansion, it gets cooled due to

Decrease in temperature
Decrease in kinetic energy
Energy spent in doing work
Decrease in velocity

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Chemical Engineering Thermodynamics
The accentric factor of a materical, 'ω', is defined as ω = -log10(Prsat)Tr⁻¹ = 0.7, where, Prsat = reduced vapor pressure, Tr = reduced temperature. The value of accentric factor is always

< 1
> 1
> 2
< 3

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Chemical Engineering Thermodynamics
In the equation, PVn = constant, if the value of n = ± ∞, then it represents a reversible __________ process.

Isothermal
Adiabatic
Isometric
Isentropic

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Chemical Engineering Thermodynamics
In an irreversible process

Tds = dE - dW = 0
Tds - dE + dW< 0
DE - dW - Tds = 0
Tds - dT + dW< 0

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