Chemical Engineering Thermodynamics
The expression, ΔG = nRT .In P₂/P₁ , gives the free energy change

Under reversible isothermal volume change
With pressure changes at constant temperature
During heating of an ideal gas
During cooling of an ideal gas

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Chemical Engineering Thermodynamics
Gibbs-Duhem equation

Finds no application in gas-liquid equilibria involved in distillation
None of these
Applies only to binary systems
States that n₁dμ₁ + n₂dμ₂ + ....njdμj = 0, for a system of definite composition at constant temperature and pressure

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Chemical Engineering Thermodynamics
Choose the condition that must be specified in order to liquify CO₂ (triple point for CO₂ is - 57°C and 5.2 atm).

Pressure must be kept below 5.2 atm. and temperature must be kept above 57°C
Pressure and temperature must be kept below 5.2 atm. and - 57°C respectively
Temperature must be kept above - 57°C
Pressure must be kept below 5.2 atm

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