Stoichiometry
The boiling points for pure water and pure toluene are 100°C and 110.6°C respectively. Toluene and water are completely immiscible in each other. A well agitated equimolar mixture of toluene and water are prepared. The temperature at which the above mixture will exert a pressure of one standard atm. is

Between 100 and 110°C
110.6°C
Less than 100°C
100°C

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Stoichiometry
The heat capacity of a substance is

Higher for solid state than for liquid state
Equal for solid and liquid states below melting point
Greater for liquid state than for solid state
Lower for liquid state than for gaseous state

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