Stoichiometry
The boiling points for pure water and pure toluene are 100°C and 110.6°C respectively. Toluene and water are completely immiscible in each other. A well agitated equimolar mixture of toluene and water are prepared. The temperature at which the above mixture will exert a pressure of one standard atm. is

110.6°C
Less than 100°C
Between 100 and 110°C
100°C

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Stoichiometry
Pick out the wrong statement about the recycle stream in a process.

Recycling in a process stream helps in utilising the valuable reactants to the maximum with minimum loss of reactants
Recycling in a process does not help in getting higher extent of reaction
The ratio of the quantity of a reactant present in the reactor feed of a recycling operation to the quantity of the same reactant entering the process as fresh feed is called combined feed ratio
Recycling is exemplified by refluxing back a part of the distillate to the distillation column to maintain the quantity of liquid within the column

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Stoichiometry
Variation of vapor pressure with temperature can be calculated using Clausius-Clapeyron equation, which assumes that the

Molal latent heat of vaporisation is constant within the limited temperature range
Volume in the liquid state is negligible compared with that in the vapor state
Vapor follows the ideal gas law
All of these

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