Chemistry
Tar roads get damaged if there is

Heavy traffic
Stagnation of water on road
No maintenance
No sloping

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Chemistry
Photo chemical smog is a resultant of the reaction among

CO, CO2 and NO2at low temperature
CO, O2 and peroxy acetyl nitrate in the presence of Sunlight
High concentration of NO2, O3, and CO in the evening
NO2, O3 and peroxy acetyl nitrate in the presence of Sunlight

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