Stoichiometry
Refluxing of part of the distillate in a fractionating column is a 'recycling operation', aimed primarily at

Heat conservation
Yield enhancement
Product enrichment
None of these

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Stoichiometry
Variation of vapor pressure with temperature can be calculated using Clausius-Clapeyron equation, which assumes that the

Volume in the liquid state is negligible compared with that in the vapor state
Vapor follows the ideal gas law
Molal latent heat of vaporisation is constant within the limited temperature range
All of these

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