Chemical Process
Platinum catalyst used in the earlier days of sulphuric acid manufacture by contact process suffers from the drawback like

All of these
Fragile nature
High cost
Easy poisoning tendency

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Chemical Process
Liquefaction of gases can not be done by

Adiabatic expansion through a throttle valve (Joule-Thomson expansion)
Exchange of heat with colder stream
Merely compressing it beyond critical pressure
Adiabatic expansion against a piston or in a turbine

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