Chemical Reaction Engineering
For a tubular reactor with space time 'τ' and residence time 'θ', the following statement holds good.

τ and θ are always equal
τ = θ , for an isothermic tubular reactor in which the density of the process fluid is constant
τ = θ , when the fluid density changes in the reactor
τ = θ , for a non-isothermal reactor

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Chemical Reaction Engineering
The rate of the heterogenous catalytic reaction A(g) + B(g) ? C(g) is given by -rA = k.KA.pA.PB/(1 + KA.PA + Kc.pc), where KA and Kc are the adsorption equilibrium constants. The rate controlling step for this reaction isA. absorption of A.

Absorption of A
Surface reaction between absorbed A and B in the gas phase
Surface reaction between A in the gas phase and absorbed B
Surface reaction between absorbed A and absorbed B

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