Stoichiometry
One kg of saturated steam at 100°C and 1.01325 bar is contained in a rigid walled vessel. It lias a volume of 1.673 m³. It cools to 98°C ; the saturation pressure is 0.943 bar ; one kg of water vapour under these conditions has a volume of 1.789 m³. The latent heat of condensation (kJ/kg⁻¹ ) under these conditions is

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Stoichiometry
According to Raoult's law, "The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component." Raoult's law is not applicable under the following assumption/condition.

The component molecules are non polar and are of almost equal size
In the formation of solution, chemical combination/molecular association between unlike molecules takes place
No component is concentrated at the surface of the solution
The attractive forces between like and unlike molecules are almost equal

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