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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Number of degrees of freedom for a three phase system in equilibrium comprising of three non-reacting chemical species is

2
3
1

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Chemical Engineering Thermodynamics
When a system is in equilibrium for all possible processes, the differential or finite change of entropy is

> 0
= 0
< 0
None of these

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Chemical Engineering Thermodynamics
Pick out the correct equation relating 'F' and 'A'.

F = A - TS
F = A + TS
F = A + PV
F = E + A

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Chemical Engineering Thermodynamics
Co-efficient of Performance (COP) of a refrigerator is the ratio of the

Lower to higher temperature
Refrigeration obtained to the work required
Work required to refrigeration obtained
Higher to lower temperature

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Chemical Engineering Thermodynamics
Which of the following identities can be most easily used to verify steam table data for superheated steam.

(∂T/∂P)S = (∂V/∂S)P
(∂P/∂T)V = (∂S/∂V)T
(∂T/∂V)S = (∂p/∂S)V
(∂V/∂T)P = -(∂S/∂P)T

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Chemical Engineering Thermodynamics
At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by(where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.)

μ° + RT ln f
μ°+ R lnf
μ° + R/T lnf
μ° + T lnf

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