Stoichiometry
No cooling occurs, when an ideal gas undergoes unrestrained expansion, because the molecules

Are above the inversion temperature
Exert no attractive force on each other
Collide without loss of energy
Do work equal to loss in kinetic energy

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Stoichiometry
Variation of vapor pressure with temperature can be calculated using Clausius-Clapeyron equation, which assumes that the

Molal latent heat of vaporisation is constant within the limited temperature range
Volume in the liquid state is negligible compared with that in the vapor state
Vapor follows the ideal gas law
All of these

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