Chemical Reaction Engineering
In the gaseous phase ammonia formation reaction (N₂ + 3H₂ ⇋ 2NH₃), the value of the equilibrium constant depends on the

Volume of the reactor
Temperature
Total pressure of the system
Initial concentration of N₂ and H₂

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Chemical Reaction Engineering
For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

Surface reaction between absorbed A and absorbed B
Surface reaction between A in the gas phase and absorbed B
Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase
Desorption of C

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