Stoichiometry
In physical adsorption, as compared to chemisorption, the

Activation energy is very high
Heat of adsorption is very large
Rate of adsorption is controlled by the resistance to surface reaction
Quantity adsorbed per unit mass is higher

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Stoichiometry
Heat of reaction is not influenced by

Whether the reaction is carried out at constant temperature or constant pressure
None of these
The physical state (e.g., solid, liquid or gaseous) of reactants and products
The route/method through which final products are obtained

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