MS Word
In order to email a Word document from within MS Word

Office button > Send to > Mail Recipient
Start Outlook and attach the file while open in Word
Save the file as an email attachment
This is an impossible operation

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MS Word
If you want to convert a symbol or several lines of text into an AutoCorrect entry, you should:

Insert the symbol or type the text in a Word document first. Then, select the text or symbol and click the Edit menu followed by Paste Special. Select New AutoCorrect Entry and then click OK.
Insert the symbol or type the text in a Word document first. Then, select the text or symbol and go to the AutoCorrect dialog box.
AutoCorrect can only accommodate one line of text. It is not possible to convert a symbol or multiple lines of text into an AutoCorrect entry.
Click the Tools menu and choose AutoCorrect Options. Then, click the Insert menu and choose Symbol (or click the Format menu and choose Paragraph) to add the symbol or paragraph to AutoCorrect.

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