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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
In an irreversible process

Tds = dE - dW = 0
Tds - dE + dW< 0
Tds - dT + dW< 0
DE - dW - Tds = 0

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Chemical Engineering Thermodynamics
When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is

Replaced by chemical potential which is more in vapour phase
Same in both the phases
More in vapour phase
More in liquid phase

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Chemical Engineering Thermodynamics
The gas law (PV = RT) is true for an __________ change.

Adiabatic
Neither A nor B
Isothermal
Both A & B

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Chemical Engineering Thermodynamics
1m³ of an ideal gas at 500 K and 1000 kPa expands reversibly to 5 times its initial volume in an insulated container. If the specific heat capacity (at constant pressure) of the gas is 21 J/mole . K, the final temperature will be

35 K
154 K
174 K
274 K

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Chemical Engineering Thermodynamics
The expression for entropy change given by, ΔS = - nR ln (P₂/P₁), holds good for

Reversible isothermal volume change
Expansion of a real gas
Heating of an ideal gas
Cooling of a real gas

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Chemical Engineering Thermodynamics
During Joule-Thomson expansion of gases

None of these
Enthalpy remains constant
Temperature remains constant
Entropy remains constant

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