Fertiliser Technology
In ammonia synthesis (N₂ + 3H₂ = 2NH₃), there is a decrease in total volume, hence to get high equilibrium conversion, the reaction should be carried out at

Atmospheric pressure; as the pressure has no effect on conversion
Very high temperature
Low pressure
High pressure

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Fertiliser Technology
Excessive use of chemical fertilisers causes shrivelling of the roots and wilting of the plant, because the

Osmotic pressure of the soil water becomes less than that of the plant sap
Soil becomes too acidic
Soil becomes too alkaline
Osmotic pressure of the soil water becomes higher than that of the plant sap

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