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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
In a homogeneous solution, the fugacity of a component depends upon the

Pressure
Temperature
All of these
Composition

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Chemical Engineering Thermodynamics
Third law of thermodynamics is helpful in

Evaluating entropy changes of chemical reaction
Prediction of the extent of a chemical reaction
Calculating absolute entropies of substances at different temperature
Both B and C

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂V/∂S)P = (∂T/∂P)S
(∂S/∂V)T = (∂P/∂T)V
(∂S/∂P)T = -(∂V/∂T)P

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Chemical Engineering Thermodynamics
Gibbs free energy per mole for a pure substance is equal to the

Chemical potential
Heat capacity
Latent heat of vaporisation
Molal boiling point

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Chemical Engineering Thermodynamics
Compressibility factor-reduced pressure plot on reduced co-ordinates facilitates

Use of only one graph for all gases
More accurate plotting
Covering of wide range
Easier plotting

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Chemical Engineering Thermodynamics
A Carnot cycle consists of the following steps :

Two isobarics and two isothermals
Two isochorics and two isobarics
Two isothermals and two isentropics
Two isothermals and two isochorics

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