Chemical Reaction Engineering
In solid catalysed reactions the diffusional effects are more likely to affect the overall rate of reaction for

Fast reactions in catalyst of small pore diameter
Fast reaction in catalyst of large pore diameter
Slow reactions in catalyst of large pore diameter
Slow reactions in catalyst of small pore diameter

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Chemical Reaction Engineering
The rate expression for a heterogenous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)

E
E + ΔHA
ΔHA + ΔHR
E + ΔHA - ΔHR

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